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where Kp Cm 0 =CD0 ; also, Kp Cm h =CA0 ; CD0 and CA0 are the aqueous solution concentrations of the uncharged species in the donor and acceptor sides, respectively In solutions saturated (ie, excess solid present) at some pH, the plot of log C0 versus pH for an ionizable molecule is extraordinarily simple in form; it is a combination of straight segments, joined at points of discontinuity indicating the boundary between the saturated state and the state of complete dissolution The pH of these junction points is dependent on the dose used in the calculation, and the maximum value of log C0 is always equal to log S0 in a saturated solution [26] Figure 22 illustrates this idea using ketoprofen as an example of an acid, verapamil as a base, and piroxicam as an ampholyte In the three cases, the assumed concentrations in the calculation were set to the respective doses [26] For an acid, log C0 (dashed curve in Fig 22a) is a horizontal line (log C0 log S0 ) in the saturated solution (at low pH), and decreases with a slope of 1 in the pH domain where the solute is dissolved completely For a base (Fig 22b) the plot of log C0 versus pH is also a horizontal line at high pH in a saturated solution and is a line with a slope of 1 for pH values less than the pH of the onset of precipitation We have called the plot of log C0 versus pH the ux factor pro le, with the idea that such a plot when combined with intrinsic permeability, can be the basis of an in vitro classi cation scheme to predict passive oral absorption as a function of pH This will be discussed later Figures 21 and 22 represent the basic model that will be used to discuss the literature related to the measurement of the physicochemical parameters and the interpretation of their role in the oral absorption process [19,20,23,45 61]. generate barcode in excel 2003 How to Use Barcode Scanners to Enter Excel Data | Your Business
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